Publications

Thesis related to the laser photolysis photoionization mass spectrometer (LP-PIMS) apparatus:

The following is a list of  the reaction kinetic group's key publications in peer-re­viewed journ­als 

 A complete list of Dr. Eskolas's publications can be found here.

    Publications related to the laser photolysis photoionization mass spectrometer (LP-PIMS) apparatus:

    1. Arkke J. Eskola, Timo T. Reijonen, Timo T. Pekkanen, Petri Heinonen, Satya P. Joshi, Raimo S. Timonen: First Direct Kinetic Measurement of i-C4H5 (CH2CHCCH2) + O2 Reaction: Toward Quantitative Understanding of Aromatic Ring Formation Chemistry. PROCEEDINGS OF THE COMBUSTION INSTITUTE, 2021, 38(1), 813–821
    2. Timo T. Pekkanen, Satya P. Joshi, György Lendvay, Raimo S. Timonen, Arkke J. Eskola: Kinetics and thermochemistry of the reaction of 1-methylpropargyl radicals with oxygen molecules: experiments and computations. PROCEEDINGS OF THE COMBUSTION INSTITUTE, 2021, 38(1), 843–852 
    3. Satya Prakash Joshi, Prasenjit Seal, Timo Theodor Pekkanen, Raimo Sakari Timonen, Arkke Johannes Eskola: Direct Kinetic Measurements and Master Equation Modelling of the Unimolecular Decomposition of Resonantly-Stabilized CH2CHCHC(O)OCH3 Radical and an Upper Limit Determination for CH2CHCHC(O)OCH3 + O2 Reaction. Z. Phys. Chem., 2020, 234, 7-9, 1251–1268
    4. S. P. Joshi, T. T Pekkanen, R. S Timonen, A. J. Eskola: Effect of Methyl Group Substitution on the Kinetics of Vinyl Radical + O2 Reaction. Journal of Physical Chemistry A, 2019, 123 (49), 10514–10519
    5. M. Döntgen, T. T. Pekkanen, S. P. Joshi, R. S. Timonen, A. J. Eskola: Oxidation Kinetics and Thermodynamics of Resonance-Stabilized Radicals: The Pent-1-en-3-yl + O2 Reaction. Journal of Physical Chemistry A, 2019, 123 (37), 7897−7910
    6. S. P. Joshi, T. T. Pekkanen, R. S. Timonen, G. Lendvay, A. J. Eskola: Kinetics of the Methyl-Vinyl Radical + O2 Reactions Associated with Propene Oxidation. Journal of Physical Chemistry A, 2019, 123 (5), 999–1006
    7. A. J. Eskola, T. T. Pekkanen, S. P. Joshi, R. S. Timonen, S. J. Klippenstein: Kinetics of 1-butyl and 2-butyl radical reactions with molecular oxygen: Experiment and theory. PROCEEDINGS OF THE COMBUSTION INSTITUTE, 2019, 37 (1), 291 – 298
    8. T. T. Pekkanen, R. S. Timonen, G. Lendvay, M. P. Rissanen, A. J. Eskola: Kinetics and thermochemistry of the reaction of 3-methylpropargyl radical with molecular oxygen. PROCEEDINGS OF THE COMBUSTION INSTITUTE, 2019, 37 (1), 299-306
    9. T. T. Pekkanen, S. L. Arppe, A. J. Eskola, M. P. Rissanen, R. S. Timonen: An Experimental Study of the Kinetics of the Reactions of Isopropyl, sec-Butyl, and tert-Butyl Radicals with Molecular Chlorine at Low Pressures (0.5–7.0 Torr) in the Temperature Range 190–480 K. International Journal of Chemical Kinetics, 2016, 48 (12), 796–805
    10. Ravi X. Fernandes, Klaus Luther, Gerd Marowsky, Matti P. Rissanen, Raimo Timonen, and Jürgen Troe: Experimental and Modeling Study of the Temperature and Pressure Dependence of the Reaction C2H5 + O2 (+M) -> C2H5O2 (+M). JOURNAL OF PHYSICAL CHEMISTRY A, 2015, 119 (28), ‏ 7263-7269 
    11. Matti P. Rissanen, Marvin Ihlenborg, Timo T. Pekkanen, and Raimo S. Timonen: Kinetics of Several Oxygen-Containing Carbon-Centered Free Radical Reactions with Nitric Oxide. JOURNAL OF PHYSICAL CHEMISTRY A, 2015, 119 (28), ‏ 7734-7741
    12. M. P. Rissanen, A. J. Eskola, T. L. Nguyen, J. R. Barker, J. Liu, J. Liu, E. Halme, and R. S. Timonen: CH2NH2 + O2 and CH3CHNH2 + O2 Reaction Kinetics: Photoionization Mass Spectrometry Experiments and Master Equation Calculations. Journal of Physical Chemistry A, 2014, 118 (12), 2176–2186
    13. Matti P. Rissanen, Suula L. Arppe, Raimo S. Timonen: Kinetics of Several Oxygenated Carbon-Centered Free Radical Reactions with NO2. JOURNAL OF PHYSICAL CHEMISTRY A, 2013, 117 (19), 3902-3908
    14. Matti P. Rissanen, Damien Amedro, Lev Krasnoperov, Paul Marshall, and Raimo S. Timonen: Gas Phase Kinetics and Equilibrium of Allyl Radical Reactions with NO and NO2JOURNAL OF PHYSICAL CHEMISTRY A, 2013, 117 (5), 793-805
    15. Matti P.Rissanen, Khushhal Popli, and Raimo S. Timonen: Kinetics of resonance stabilized CH3CCCH2 radical reactions with NO and NO2CHEMICAL PHYSICS LETTERS, 2012, 543, 28-33
    16. Matti P. Rissanen, Arkke J. Eskola, Raimo S. Timonen: Kinetics of the brominated alkyl radical (CHBr2, CH3CHBr) reactions with NO2 in the temperature range 250 ‒ 480 K. International Journal of Chemical Kinetics, 2012, 44(12), 767‒777
    17. Matti P. Rissanen, Damien Amedro, Arkke J. Eskola, Theo Kurten, Raimo S. Timonen: Kinetic (T = 201 ‒ 298 K) and Equilibrium (T = 320 ‒ 420 K) Measurements of the C3H5 + O2 ↔ C3H5O2 Reaction. Journal of Physical Chemistry A, 2012, 116(16), 3969–3978
    18. Matti P. Rissanen, Suula L. Arppe, Arkke J. Eskola, Matti M. Tammi, Raimo S. Timonen: Kinetics of the R + NO2 reactions (R= i-C3H7, n-C3H7, s-C4H9 and t-C4H9) in the temperature range 201 – 489 K. Journal of Physical Chemistry A, 2010, 114(14), 4811 – 4817
    19. Matti P. Rissanen, Arkke J. Eskola, Raimo S. Timonen: Kinetics of the reactions of CH2Cl, CH3CHCl and CH3CCl2 radicals with Cl2 in the temperature range 191 – 363 K. Journal of Physical Chemistry A, 2010, 114(14), 4805 – 4810
    20. Matti P. Rissanen, Arkke J. Eskola, Elena Savina, Raimo S. Timonen: Kinetics of the Reactions of CH3CH2, CH3CHCl, and CH3CCl2 Radicals with NO2 in the Temperature Range 221– 363 K. Journal of Physical Chemistry A, 2009, 113(9), 1753-1759 
    21. Arkke J. Eskola, Raimo S. Timonen, Paul Marshall, Evgeni N. Chesnokov, Lev N. Krasnoperov: Rate Constants and Hydrogen Isotope Substitution Effects in the CH3 + HCl and CH3 + Cl2 Reactions. Journal of Physical Chemistry A, 2008, 112(32), 7391-7401
    22. Arkke J. Eskola, Iwona Golonka, Matti P. Rissanen, Raimo S. Timonen: Kinetics of the CCl2 +Br2 and CCl2 +NO2 reactions in the temperature range 266 − 365K and reactivity of the CCl2 biradical. Chemical Physics Letters, 2008, 460(4-6), 401-405
    23. Jorma A. Seetula, Arkke J. Eskola: Kinetics of the R + HBr ↔ RH + Br (CH3CHBr, CHBr2 or CDBr2) equilibrium. Thermochemistry of the CH3CHBr and CHBr2 radicals. Chemical Physics, 2008, 351, 1-3
    24. Arkke J. Eskola, Vladimir A. Lozovsky, Raimo S. Timonen: Kinetics of the Reactions of C2H5, n-C3H7, and n-C4H9 Radicals with Cl2 at the Temperature Range 190 – 360 K. Int. J. Chem. Kinet., 2007, 39, 614-619
    25. Arkke J. Eskola, Jorma J. Seetula, Raimo S. Timonen: Kinetics of the of CH3 + HCl/DCl → CH4/CH3D + Cl and CD3 + HCl/DCl → CD3H/CD4 + Cl reactions: An experimental H atom tunneling investigation. Chemical Physics, 2006, 331, 26-34
    26. Arkke J. Eskola, Dorota Wojcik-Pastuszka, Emil Ratajczak, Raimo S. Timonen: Kinetics of the reactions of CH2I, CH2Br, and CHBrCl radicals with NO2 in the temperature range 220 − 360 K. J. Phys. Chem. A, 2006, 110, 12177-12183
    27. Arkke J. Eskola, Dorota Wojcik-Pastuszka, Emil Ratajczak, Raimo S. Timonen: Kinetics of the reactions of CH2Br and CH2I radicals with molecular oxygen at atmospheric temperatures. Phys. Chem. Chem. Phys., 2006, 8, 1416-1424 
    28. Arkke J. Eskola, Wolf D. Geppert, Matti P. Rissanen, Raimo S. Timonen, Lauri Halonen: Kinetics of the reactions of chlorinated methyl radicals (CH2Cl, CHCl2, and CCl3) with NO2 in the temperature range 220 − 360 K. J. Phys. Chem. A, 2005, 109, 5376-5381
    29. W. D. Geppert, A. J. Eskola, R. S. Timonen, L. Halonen: Kinetics of the reactions of vinyl (C2H3) and propargyl (C3H3) radicals with NO2 in the temperature range 220 – 340 K. J. Phys. Chem. A, 2004, 108, 4232-4238
    30. A. J. Eskola, R. S. Timonen: Kinetics of the reactions of vinyl radicals with molecular oxygen and chlorine at temperatures 200 – 362 K. Phys. Chem. Chem. Phys., 2003, 5, 2557-2561

    Publications related to the time-resolved, broadband, cavity-enhanced absorption spectrometer (TR-BB-CEAS) apparatus:

    1. Jari Peltola, Prasenjit Seal, Anni Inkilä and Arkke Eskola: Time-resolved, broadband UV-absorption spectrometry measurements of Criegee intermediate kinetics using a new photolytic precursor: Unimolecular decomposition of CH2OO and its reaction with formic acid. Phys. Chem. Chem. Phys., 2020, 22: 11797 – 11808